Хлорид йода

162.36

162.36

3902972

232-236-7

0SMG5NLU45

1792

DTXSID1064879

BLACK CRYSTALS OR REDDISH-BROWN LIQ

2812104900

0

2.51

Red-brown Liquid

3.10 g/cm³ @ Temp: 29 °C

27.19 °C

97.4 °C(lit.)

96-98°C

1.592

Decomposes in water;acetic acid: soluble (lit.)

2-8°C

Oral-Rat LDL0: 50 mg/kg

In case of H, the pore-forming agent is flammable; in case of cyanide, it produces highly toxic gas; high-temperature decomposition of toxic chlorine and iodide fumes

When heated to decomposition, it emits highly toxic fumes of /hydrogen chloride and hydrogen iodide/ and may explode.

CRYSTALS OCCUR IN ALPHA (STABLE) & BETA (LABILE) FORMS|BLACK NEEDLES (RUBY RED BY TRANSMITTED LIGHT) /ALPHA FORM/; BLACK PLATELETS (BROWNISH RED BY TRANSMITTED LIGHT) /BETA FORM/|RHOMBIC 6-SIDED PLATES /BETA/; NEEDLES, CUBIC /ALPHA/

Reacts with air to form iodine pentaoxide (I2O5), which decomposes into iodine (I2) and oxygen (O2) with heat beginning at 275°C and proceeding rapidly at 350°C. Soluble in water; reacts with water or steam to produce toxic and corrosive fumes [Lewis].

Oxidizing Agents, Strong

Strong Oxidizing Agent

IODINE MONOCHLORIDE is moderately explosive when heated [Lewis]. Reacts with rubber and many organic materials. Enflames (after a period of delay) with aluminum foil [Mellor 2:119(1946-1947)]. Reacts dangerously with other active metals. Reacts vigorously with cadmium sulfide, lead sulfide, silver sulfide, and zinc sulfide [Mellor 2, Supp. 1:502(1956)]. Combines very exothermically with phosphorus trichloride [Mellor 2, Supp. 1:502(1956)]. Forms Iodine pentaoxide in air which reacts explosively when warmed with carbon, sulfur, sugar, resin, or powdered combustible elements [Mellor 8: 841(1946-1947)].

II

8

UN 1792 8/PG 2

3

34-42-35-10-40-67-37

26-36/37/39-45-23

NN1650000

C

The warehouse is ventilated and dried at low temperature; stored separately from alkalis, reducing agents, cyanide and H pore-forming agents.

High thermal decomposition of chlorine and iodine gas can be explosive; hydrolysate is corrosive to the skin and cornea

Stable. Incompatible with organic materials, strong bases, metals. Air, light and moisture sensitive.

P261-P280-P305 + P351 + P338-P310

H314-H334

IODINE MONOCHLORIDE PRODUCES VIGOROUS REACTION WITH CORK, RUBBER, & OTHER ORGANIC SUBSTANCES. PHOSPHORUS REACTS VIOLENTLY WITH MOLTEN...IODINE MONOCHLORIDE. REACTION.../WITH/ PHOSPHORUS TRICHLORIDE IS INTENSELY EXOTHERMAL. ...REACTION OF SODIUM IS VERY SLOW.|WILL REACT WITH WATER OR STEAM, TO PRODUCE TOXIC & CORROSIVE FUMES.|REACTION BETWEEN IODINE MONOCHLORIDE & CADMIUM SULFIDE, LEAD SULFIDE, SILVER SULFIDE, OR ZINC SULFIDE IS VIGOROUS.

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. For UN1796, UN1826, UN2031 at high concentrations and for UN2032, these may act as oxidizers, also consult ERG Guide 140. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Substance may react with water (some violently), releasing corrosive and/or toxic gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. (ERG, 2016)

|Danger|H300 (18.64%): Fatal if swallowed [Danger Acute toxicity, oral]|P260, P261, P264, P270, P271, P280, P285, P301+P310, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P304+P341, P305+P351+P338, P310, P312, P321, P322, P330, P342+P311, P361, P363, P403+P233, P405, and P501|Aggregated GHS information provided by 59 companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: Note: Some foams will react with the material and release corrosive/toxic gases. SMALL FIRE: CO2 (except for Cyanides), dry chemical, dry sand, alcohol-resistant foam. LARGE FIRE: Water spray, fog or alcohol-resistant foam. Move containers from fire area if you can do it without risk. Use water spray or fog; do not use straight streams. Dike fire-control water for later disposal; do not scatter the material. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. (ERG, 2016)

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. SPILL: Increase, in the downwind direction, as necessary, the isolation distance shown above. FIRE: If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2016)

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). All equipment used when handling the product must be grounded. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. A vapor-suppressing foam may be used to reduce vapors. DO NOT GET WATER INSIDE CONTAINERS. Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. Prevent entry into waterways, sewers, basements or confined areas. SMALL SPILL: Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Use clean, non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal. (ERG, 2016)

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. (ERG, 2016)

ALUMINUM FOIL, AFTER CONTINUED CONTACT WITH IODINE MONOCHLORIDE, IGNITES SPONTANEOUSLY & BURNS WITH BLUISH-WHITE FLAME.

POTASSIUM EXPLODES IN CONTACT WITH IODINE MONOCHLORIDE.|When heated to decomposition, it emits highly toxic fumes of /hydrogen chloride and hydrogen iodide/ and may explode.

BASIC...METHODS ARE LOCAL EXHAUST...& DIL OR GENERAL VENTILATION.

/GUIDE 157: SUBSTANCES - TOXIC AND/OR CORROSIVE (NON-COMBUSTIBLE/WATER -SENSITIVE)/ Health: TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns, or death. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat which will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.|/GUIDE 157: SUBSTANCES - TOXIC AND/OR CORROSIVE (NON-COMBUSTIBLE/WATER -SENSITIVE)/ Fire or Explosion: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or contaminated with water.|/GUIDE 157: SUBSTANCES - TOXIC AND/OR CORROSIVE (NON-COMBUSTIBLE/WATER -SENSITIVE)/ Public Safety: CALL Emergency Response Telephone Number ... . As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids. Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate enclosed areas.|/GUIDE 157: SUBSTANCES - TOXIC AND/OR CORROSIVE (NON-COMBUSTIBLE/WATER -SENSITIVE)/ Protective Clothing: Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible.|For more DOT Emergency Guidelines (Complete) data for IODINE MONOCHLORIDE (8 total), please visit the HSDB record page.

No person may /transport,/ offer or accept a hazardous material for transportation in commerce unless that person is registered in conformance ... and the hazardous material is properly classed, described, packaged, marked, labeled, and in condition for shipment as required or authorized by ... /the hazardous materials regulations (49 CFR 171-177)./|The International Maritime Dangerous Goods Code lays down basic principles for transporting hazardous chemicals. Detailed recommendations for individual substances and a number of recommendations for good practice are included in the classes dealing with such substances. A general index of technical names has also been compiled. This index should always be consulted when attempting to locate the appropriate procedures to be used when shipping any substance or article.